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Người gửi: Trần Văn Dương
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Nguồn:
Người gửi: Trần Văn Dương
Ngày gửi: 17h:18' 29-09-2023
Dung lượng: 4.7 MB
Số lượt tải: 77
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0 người
2. DIVERSITY OF MATTER
Eclipse
(Pink Floyd –The Dark side of the
Moon)
All that you touch
All that you see
All that you taste
All you feel
All that you love
All that you hate
All you distrust
All you save
All that you give
All that you deal
All that you buy
beg, borrow or steal
All you create
All you destroy
All that you do
All that you say
All that you eat
everyone you meet
All that you slight
everyone you fight
All that is now
All that is gone
All that's to come
And everything under the sun is in tune (*)
But the sun is eclipsed by the moon.
And is made of MATTER!
…Matter is anything that occupies
space.
States of Matter
The
Four States of
Matter
Solid
Liquid
Gas
Plasma
4
States of Matter
The Four States of
Matter
Basis
of Classification of the Four
Types
Based
upon particle arrangement
Based upon energy of particles
Based upon distance between
particles
5
States of Matter
Solids
Particles of solids are tightly packed, vibrating
about a fixed position.
Solids have a definite shape and a definite
volume.
Solids have an infinite number of free surfaces.
6
States of Matter
Microscopic Explanation for Properties of
Solids
Solids have a definite shape and a definite
volume
because the particles are locked into place
Solids are not easily compressible because
there is little free space between particles
Solids do not flow easily because the
particles cannot move/slide past one another
7
States of Matter
Liquids
Particles of liquids are tightly packed, but are
far enough apart to slide over one another.
Liquids have an indefinite shape and a definite
volume.
Liquids have one free surface.
8
States of Matter
Microscopic Explanation for Properties of
Liquids
Liquids have an indefinite shape because the
particles can slide past one another.
Liquids are not easily compressible and have
a definite volume because there is little free
space between particles.
Liquids flow easily because the particles can
move/slide past one another.
9
States of Matter
Gases
Particles of gases are very far apart and move freely.
Gases have an indefinite shape and an indefinite
volume.
Gases have no free surfaces.
10
States of Matter
Microscopic Explanation for Properties of
Gases
Gases have an indefinite shape and an
indefinite volume because the particles can
move past one another.
Gases are easily compressible because there
is a great deal of free space between
particles.
Gases flow very easily because the particles
randomly move past one another.
11
States of Matter
Plasma
A plasma is an ionized gas at very high
temperature.
A plasma is a very good conductor of
electricity and is affected by magnetic fields.
It is is by far the most common form of
matter. Plasma in the stars and in the
tenuous space between them makes up over
99% of the visible universe and perhaps
most of that which is not visible.
12
States of Matter
13
States of Matter
Microscopic Explanation for Properties of
Plasmas
Plasmas have an indefinite shape and an
indefinite volume because the particles can
move past one another.
Plasmas are easily compressible because
there is a great deal of free space between
particles.
Plasmas are good conductors of electricity
and are affected by magnetic fields because
they are composed of ions (negatively
charged electrons and positively charged
nuclei).
14
States of Matter
The Four States of
Matter
The
Classification and Properties of
Matter Depend Upon Microscopic
Structure
Particle
Particle
Particle
arrangement
energy
to particle distance
15
Gases, Solids, and Liquids
Particle Properties
Phase
Spacing
Energy
Motion
Volume
Shape
Solid
close
low
vibrational
definite
definite
Liquid
close
moderate
rotational
definite
indefinite
far apart
high
translational
indefinite
indefinite
Gas
Physical
properties are those that
we can determine without
changing the identity of the
substance we are studying.
The physical properties can be observed or measured.
Hardness, color, melting point and density are all physical properties
Intensive
properties do not
depend on the size of the
sample of matter and can be
used to identify substances.
density, color, melting and boiling
point , …..
Extensive
properties depend on
the quantity of the sample.
mass , area, volume, …
All matter, regardless of state, undergoes
physical and chemical changes.
A physical change occurs when the substance changes state but does
not change its chemical composition.
For example:
•water freezing into ice
•cutting a piece of wood into smaller pieces
•breaking a paper
The form or appearance has changed, but the physical properties of
that substance are the same:
Melting point Density Boiling point Color Vapor pressure
Electrical conductivity Solubility Hardness……
Chemical
properties describe the
way a substance can change or
react to form other
substances. These properties,
then, must be determined using a
process that changes the identity
of the substance of interest.
A chemical change occurs when a substance
changes into something new.
This occurs due to heating, chemical reaction, etc. You can tell a
chemical change has occurred if the density, melting point or freezing
point of the original substance changes. Many common signs of a
chemical change can be seen (bubbles forming, mass or colour
changed, etc).
Mixtures are two or more substances that are NOT
chemically combined.
Mixtures do not:
· Have constant boiling points
· Have constant melting points
Variable
composition
Components retain their
characteristic properties
May be separated into pure
substances by physical methods
Mixtures of different
compositions may have widely
different properties
Heterogeneous
mixtures are
composed of large pieces that are
easily separated by physical means
(ie. density, polarity, metallic
properties).
Do
not have same composition
throughout
Components
are distinguishable
Examples: fruit salad, vegetable soup,
wood, granite, etc.
Solutions are homogenous. Therefore, they are easily
separated by physical methods like distillation or
evaporation.
Examples:
• Sugar /water
• Stainless steel
• Salt / water
• Wine
• Brass
• Air
• Cola drink
Separating Mixtures
Dirty
water
Oil and
Water
Saltwate
r
Settling
Density
causes
parts of the mixture
to settle to the
bottom.
This
process is used
during water
filtration.
Contaminants sink
and clearer water is
skimmed off.
31
MAGNETIC
To separate a magnetic component from a
mixture containing non- magnetic
components
(e.g. iron and sand or sulphur).
Decantation
Decanting is the
simplest possible way of
separating a liquid (pure
or a solution) from an
insoluble solid which
has a density greater
than water
A mixture of two
immiscible liquids can
also be separated by
Filtration
A
mixture is
passed through
material with
many holes.
Anything larger
than the hole is
trapped while the
rest of the
mixture passes
through.
Examples:
Dirty water lab
34
Crystallization
The
separation
process in which
the solvent is
evaporated,
leaving crystals
of solute behind.
◦ Examples:
Rock candy
Saltwater lab
35
The
Distillation
separation process in which the desired
component is evaporated from the solution
and collected.
Water is boiled and the steam is collected. As
the steam cools, it condenses to form pure
water and anything that was dissolved in the
water is left behind
36
Chromatography
This
process is mostly
used to identify
substances.
As the substance is
drawn up the material
(e.g., filter paper), it
carries the solutes
with it.
The least dense are
drawn farthest up the
filter paper.
Example:
37
A substance is matter of a particular kind.
A substance cannot be further broken down or
purified by physical means.
Each substance has its own characteristic properties
that are different from the set of properties of any
other substance.
Fixed
composition
Properties
do not vary
Cannot
be separated into simpler substances
by physical methods (physical changes)
Can
only be changed in identity and
properties by chemical methods
Compounds
Can
be decomposed
into simpler
substances by
chemical changes,
always in a definite
ratio*
Elements
Cannot
be decomposed
into simpler substances
by chemical changes
Gold
Iron
Sulfur
Oxygen
Chlorine
Water
Sugar
Salt
Ammonia
* Water always contains 88,9 % oxygen and 11,1 % hydrogen
Propane
MATERIAL SYSTEM
HAS IT UNIFORM PROPERTIES?
YES
NO: MIXTURE
HOMOGENEOUS
HETEROGENEOUS
Wood
Granite
Hamburger
Pencil
Has it always the same
composition and properties?
NO: MIXTURE
SOLUTION
drinking water
Bronze
Air
Bleach
Coca-Cola
YES: PURE SUBSTANCE
Can it be broken down into a simpler substance
by a chemical reaction?
NO
YES
COMPOUND
Water
Sugar
Sulfuric acid
Salt
ELEMENT
Gold
Oxygene
Copper
Solutions
Definitions
A
solution is a homogeneous mixture
A
solute is dissolved in a solvent.
Solute is present in the smaller amount
The solvent is present in the larger
amount.
an aqueous solution has water as solvent
*ey-kwee-uhs
Solutions
a homogenous mixture of 2 or more
substances
Solvent
Solute
the substance
present in the
larger amount
is(are) the
substance(s)
present in the
smaller
amount(s)
When the solvent is water the solution is
said to be aqueous
Types of solutions
Gases
Gases dissolved in gases (air)
Liquids dissolved in gases (humid air)
Solids dissolved in gases (moth balls *)
Liquids
Gases in liquids (air dissolved in water)
Liquids in liquids (ethanol in water)
Solids in Liquids (salt in water)
Solids
Gases in solids (H2 in Pt)
Liquids in solids (Hg/Ag amalgam)
Solids in solids (Cr in Fe alloy)
(*) bolas antipolilla
Terminology
Solubility: The maximum amount of solute that will dissolve in
a solvent.
Dilute: A solution that contains relatively little solute.
Concentrated: A solution that contains a relatively large
amount of solute.
Saturated: is one where the concentration is at a maximum no more solute is able to dissolve.
Supersaturated: A solution that contains more than the
solubility limit.
Concentration
Concentration is the amount of solute in a given amount
of either solution or solvent
mass solute
% (w / w )
mass solution
% (v / v )
g/L
volume solute
volume solution
grams of solute
liters of solution
x 100
x 100
Factors Affecting Solubility
1. Nature of Solute / Solvent.
- Like dissolves like
2. Temperature -
Solids/Liquids- Solubility increases with Temperature
Gases - Solubility decreases with Temperature
3. Pressure Factor -
Solids/Liquids - Very little effect
Gas - Solubility increases with Pressure.
Solubilities of Solids vs
Temperature
Solubilities of Gases vs
Temperature
Eclipse
(Pink Floyd –The Dark side of the
Moon)
All that you touch
All that you see
All that you taste
All you feel
All that you love
All that you hate
All you distrust
All you save
All that you give
All that you deal
All that you buy
beg, borrow or steal
All you create
All you destroy
All that you do
All that you say
All that you eat
everyone you meet
All that you slight
everyone you fight
All that is now
All that is gone
All that's to come
And everything under the sun is in tune (*)
But the sun is eclipsed by the moon.
And is made of MATTER!
…Matter is anything that occupies
space.
States of Matter
The
Four States of
Matter
Solid
Liquid
Gas
Plasma
4
States of Matter
The Four States of
Matter
Basis
of Classification of the Four
Types
Based
upon particle arrangement
Based upon energy of particles
Based upon distance between
particles
5
States of Matter
Solids
Particles of solids are tightly packed, vibrating
about a fixed position.
Solids have a definite shape and a definite
volume.
Solids have an infinite number of free surfaces.
6
States of Matter
Microscopic Explanation for Properties of
Solids
Solids have a definite shape and a definite
volume
because the particles are locked into place
Solids are not easily compressible because
there is little free space between particles
Solids do not flow easily because the
particles cannot move/slide past one another
7
States of Matter
Liquids
Particles of liquids are tightly packed, but are
far enough apart to slide over one another.
Liquids have an indefinite shape and a definite
volume.
Liquids have one free surface.
8
States of Matter
Microscopic Explanation for Properties of
Liquids
Liquids have an indefinite shape because the
particles can slide past one another.
Liquids are not easily compressible and have
a definite volume because there is little free
space between particles.
Liquids flow easily because the particles can
move/slide past one another.
9
States of Matter
Gases
Particles of gases are very far apart and move freely.
Gases have an indefinite shape and an indefinite
volume.
Gases have no free surfaces.
10
States of Matter
Microscopic Explanation for Properties of
Gases
Gases have an indefinite shape and an
indefinite volume because the particles can
move past one another.
Gases are easily compressible because there
is a great deal of free space between
particles.
Gases flow very easily because the particles
randomly move past one another.
11
States of Matter
Plasma
A plasma is an ionized gas at very high
temperature.
A plasma is a very good conductor of
electricity and is affected by magnetic fields.
It is is by far the most common form of
matter. Plasma in the stars and in the
tenuous space between them makes up over
99% of the visible universe and perhaps
most of that which is not visible.
12
States of Matter
13
States of Matter
Microscopic Explanation for Properties of
Plasmas
Plasmas have an indefinite shape and an
indefinite volume because the particles can
move past one another.
Plasmas are easily compressible because
there is a great deal of free space between
particles.
Plasmas are good conductors of electricity
and are affected by magnetic fields because
they are composed of ions (negatively
charged electrons and positively charged
nuclei).
14
States of Matter
The Four States of
Matter
The
Classification and Properties of
Matter Depend Upon Microscopic
Structure
Particle
Particle
Particle
arrangement
energy
to particle distance
15
Gases, Solids, and Liquids
Particle Properties
Phase
Spacing
Energy
Motion
Volume
Shape
Solid
close
low
vibrational
definite
definite
Liquid
close
moderate
rotational
definite
indefinite
far apart
high
translational
indefinite
indefinite
Gas
Physical
properties are those that
we can determine without
changing the identity of the
substance we are studying.
The physical properties can be observed or measured.
Hardness, color, melting point and density are all physical properties
Intensive
properties do not
depend on the size of the
sample of matter and can be
used to identify substances.
density, color, melting and boiling
point , …..
Extensive
properties depend on
the quantity of the sample.
mass , area, volume, …
All matter, regardless of state, undergoes
physical and chemical changes.
A physical change occurs when the substance changes state but does
not change its chemical composition.
For example:
•water freezing into ice
•cutting a piece of wood into smaller pieces
•breaking a paper
The form or appearance has changed, but the physical properties of
that substance are the same:
Melting point Density Boiling point Color Vapor pressure
Electrical conductivity Solubility Hardness……
Chemical
properties describe the
way a substance can change or
react to form other
substances. These properties,
then, must be determined using a
process that changes the identity
of the substance of interest.
A chemical change occurs when a substance
changes into something new.
This occurs due to heating, chemical reaction, etc. You can tell a
chemical change has occurred if the density, melting point or freezing
point of the original substance changes. Many common signs of a
chemical change can be seen (bubbles forming, mass or colour
changed, etc).
Mixtures are two or more substances that are NOT
chemically combined.
Mixtures do not:
· Have constant boiling points
· Have constant melting points
Variable
composition
Components retain their
characteristic properties
May be separated into pure
substances by physical methods
Mixtures of different
compositions may have widely
different properties
Heterogeneous
mixtures are
composed of large pieces that are
easily separated by physical means
(ie. density, polarity, metallic
properties).
Do
not have same composition
throughout
Components
are distinguishable
Examples: fruit salad, vegetable soup,
wood, granite, etc.
Solutions are homogenous. Therefore, they are easily
separated by physical methods like distillation or
evaporation.
Examples:
• Sugar /water
• Stainless steel
• Salt / water
• Wine
• Brass
• Air
• Cola drink
Separating Mixtures
Dirty
water
Oil and
Water
Saltwate
r
Settling
Density
causes
parts of the mixture
to settle to the
bottom.
This
process is used
during water
filtration.
Contaminants sink
and clearer water is
skimmed off.
31
MAGNETIC
To separate a magnetic component from a
mixture containing non- magnetic
components
(e.g. iron and sand or sulphur).
Decantation
Decanting is the
simplest possible way of
separating a liquid (pure
or a solution) from an
insoluble solid which
has a density greater
than water
A mixture of two
immiscible liquids can
also be separated by
Filtration
A
mixture is
passed through
material with
many holes.
Anything larger
than the hole is
trapped while the
rest of the
mixture passes
through.
Examples:
Dirty water lab
34
Crystallization
The
separation
process in which
the solvent is
evaporated,
leaving crystals
of solute behind.
◦ Examples:
Rock candy
Saltwater lab
35
The
Distillation
separation process in which the desired
component is evaporated from the solution
and collected.
Water is boiled and the steam is collected. As
the steam cools, it condenses to form pure
water and anything that was dissolved in the
water is left behind
36
Chromatography
This
process is mostly
used to identify
substances.
As the substance is
drawn up the material
(e.g., filter paper), it
carries the solutes
with it.
The least dense are
drawn farthest up the
filter paper.
Example:
37
A substance is matter of a particular kind.
A substance cannot be further broken down or
purified by physical means.
Each substance has its own characteristic properties
that are different from the set of properties of any
other substance.
Fixed
composition
Properties
do not vary
Cannot
be separated into simpler substances
by physical methods (physical changes)
Can
only be changed in identity and
properties by chemical methods
Compounds
Can
be decomposed
into simpler
substances by
chemical changes,
always in a definite
ratio*
Elements
Cannot
be decomposed
into simpler substances
by chemical changes
Gold
Iron
Sulfur
Oxygen
Chlorine
Water
Sugar
Salt
Ammonia
* Water always contains 88,9 % oxygen and 11,1 % hydrogen
Propane
MATERIAL SYSTEM
HAS IT UNIFORM PROPERTIES?
YES
NO: MIXTURE
HOMOGENEOUS
HETEROGENEOUS
Wood
Granite
Hamburger
Pencil
Has it always the same
composition and properties?
NO: MIXTURE
SOLUTION
drinking water
Bronze
Air
Bleach
Coca-Cola
YES: PURE SUBSTANCE
Can it be broken down into a simpler substance
by a chemical reaction?
NO
YES
COMPOUND
Water
Sugar
Sulfuric acid
Salt
ELEMENT
Gold
Oxygene
Copper
Solutions
Definitions
A
solution is a homogeneous mixture
A
solute is dissolved in a solvent.
Solute is present in the smaller amount
The solvent is present in the larger
amount.
an aqueous solution has water as solvent
*ey-kwee-uhs
Solutions
a homogenous mixture of 2 or more
substances
Solvent
Solute
the substance
present in the
larger amount
is(are) the
substance(s)
present in the
smaller
amount(s)
When the solvent is water the solution is
said to be aqueous
Types of solutions
Gases
Gases dissolved in gases (air)
Liquids dissolved in gases (humid air)
Solids dissolved in gases (moth balls *)
Liquids
Gases in liquids (air dissolved in water)
Liquids in liquids (ethanol in water)
Solids in Liquids (salt in water)
Solids
Gases in solids (H2 in Pt)
Liquids in solids (Hg/Ag amalgam)
Solids in solids (Cr in Fe alloy)
(*) bolas antipolilla
Terminology
Solubility: The maximum amount of solute that will dissolve in
a solvent.
Dilute: A solution that contains relatively little solute.
Concentrated: A solution that contains a relatively large
amount of solute.
Saturated: is one where the concentration is at a maximum no more solute is able to dissolve.
Supersaturated: A solution that contains more than the
solubility limit.
Concentration
Concentration is the amount of solute in a given amount
of either solution or solvent
mass solute
% (w / w )
mass solution
% (v / v )
g/L
volume solute
volume solution
grams of solute
liters of solution
x 100
x 100
Factors Affecting Solubility
1. Nature of Solute / Solvent.
- Like dissolves like
2. Temperature -
Solids/Liquids- Solubility increases with Temperature
Gases - Solubility decreases with Temperature
3. Pressure Factor -
Solids/Liquids - Very little effect
Gas - Solubility increases with Pressure.
Solubilities of Solids vs
Temperature
Solubilities of Gases vs
Temperature
 







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